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- W2082952469 abstract "Some chloromanganese(III) Schiff base complexes react with hydrogen chloride to give deep green complexes with the empirical formula of MnLCl2 or MnL′2Cl2, where H2L denotes quadridentate ligands such as N,N′-disalicylideneethylenediamine and its analogs, and where HL′ denotes bidentate ligands such as N-butylsalicylideneamine and its analogs. These complexes are nonelectrolytes in acetonitrile. Their magnetic moments at room temperature fall within the range of 3.9 to 4.1 BM, and the magnetic susceptibilities obey the Curie-Weiss law with small θ values over the temperature range of 77 to 300 K, indicating that the oxidation state of the manganese ions in these complexes is +IV. The electronic spectra show an intense band around 16000 cm−1 which can be assigned to a charge-transfer transition. In the cyclic voltammograms, two cathodic waves are observed at half-peak potentials around +0.9 V and −0.2 V(vs. SCE); they can be assigned to the reductions of Mn(IV) to Mn(III) and of Mn(III) to Mn(II) respectiv..." @default.
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- W2082952469 date "1981-09-01" @default.
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- W2082952469 title "The Preparation and Characterization of Dichloromanganese(IV) Schiff Base Complexes" @default.
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