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• W2082962012 abstract "A novel nonlinear optical crystal [C3N2H5+][Br-] has been synthesized and characterized by a single-crystal X-ray diffraction, calorimetric, dilatometric and dielectric measurements. Above 200 K the crystal structure is polar, with symmetry R3. It consists of a highly disordered imidazolium cations and discrete Br- anions. The compound reveals a first order phase transition at 199/201 K (cooling/heating cycle) which leads to the monoclinic centrosymmetric space group P21/m. The exceptionally large increment of dielectric permittivity accompaning the structure transformation is related to the freezing of cation motions and a significant rebuilding of the anionic substructure." @default.
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• W2082962012 date "2011-02-01" @default.
• W2082962012 modified "2023-10-17" @default.
• W2082962012 title "Crystal structure and characterization of a novel acentric imidazolium analog <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si14.gif overflow=scroll><mml:mrow><mml:mo stretchy=false>[</mml:mo><mml:msub><mml:mrow><mml:mtext>C</mml:mtext></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mtext>N</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msubsup><mml:mrow><mml:mtext>H</mml:mtext></mml:mrow><mml:mrow><mml:…" @default.
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• W2082962012 doi "https://doi.org/10.1016/j.cplett.2010.12.083" @default.
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