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- W2082976573 abstract "The new copolymeric series {[NP(O2C12H8)]1−x[NP(NHBun)2]x}n (O2C12H82,2′-dioxy-1,1′-biphenyl) with x = 0.1(1a), 0.31(1b), 0.43(1c), 0.63(1d) were prepared by the alkali carbonate-assisted sequential macromolecular substitution from [NPCl2]n. The thermal gravimetric analysis (TGA) revealed that although the stability decreased with x, the final residues (ca. 50% at 800 °C under N2; 30% at 900 °C under air; and 15% at 1100 °C under oxygen) were unusually high. The variation of the glass transition temperatures with x showed negative deviation from the additive values (Fox equation), probably due to the losing of hydrogen bonding contribution as x is decreased." @default.
- W2082976573 created "2016-06-24" @default.
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- W2082976573 date "2011-03-01" @default.
- W2082976573 modified "2023-10-06" @default.
- W2082976573 title "Polyphosphazenes combining dioxybiphenyl and butyl-amino substituents, a series with unusually high TGA residues and glass transition temperatures with negative deviation from additivity" @default.
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- W2082976573 doi "https://doi.org/10.1016/j.eurpolymj.2010.11.019" @default.
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