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- W2083002352 abstract "This report establishes that trigonally coordinated “[PhBPiPr3]M” platforms (M = Fe, Co) will support both π-acidic (N2) and π-basic (NR) ligands at a fourth binding site. The N2 complexes of iron that are described are the first thoroughly characterized examples to exhibit a 4-coordinate geometry. Methylation of monomeric {Fe0(N2)-} and {Co0(N2)-} species successfully derivatizes the β-N atom of the coordinated N2 ligand and affords the diazenido products {FeII(N2Me)} and {CoII(N2Me)}, respectively. One-electron oxidation of the mononuclear M0(N2)- species produces dinuclear and synthetically versatile MI(N2)MI complexes. These latter species provide clean access to the chemistry of the “[PhBPiPr3]MI” subunit. For example, addition of RN3 to MI(N2)MI results in oxidative nitrene transfer to generate [PhBPiPr3]M⋮NR with concomitant N2 release." @default.
- W2083002352 created "2016-06-24" @default.
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- W2083002352 date "2003-08-15" @default.
- W2083002352 modified "2023-10-16" @default.
- W2083002352 title "Dinitrogen Chemistry from Trigonally Coordinated Iron and Cobalt Platforms" @default.
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- W2083002352 doi "https://doi.org/10.1021/ja036687f" @default.
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