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- W2083008575 abstract "Rate constants and activation energies of several one-electron transfer reactions from organic anion radicals to neutral oranganic molecules in aqueous mixtures of methanol, ethanol, 1-propanol, glycerol, and urea were determined by the technique of pulse radiolysis. The solvent effect is more pronounced for slow than fast tion rates between species with the same functional groups. Kinetic parameters of the reaction change in a complicated manner with variations of the binary mixture content. The dependence cannot be explained by Marcus' theory for electron transfer reactions. Composition of the solvent closely surrounding the reacting species and their short-range interactions must be considered if a better understanding of the kinetics is to be achieved. (auth)" @default.
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- W2083008575 date "1974-01-01" @default.
- W2083008575 modified "2023-09-25" @default.
- W2083008575 title "Solvent participation in electron transfer reactions" @default.
- W2083008575 doi "https://doi.org/10.1021/j100596a020" @default.
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