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- W2083009718 abstract "The retention behaviors of polybutadiene-coated titania stationary phase (PBD-TiO2) are investigated by the use of linear solvation energy relationships (LSERs) of 21 solutes. The logarithmic capacity factors measured on PBD-TiO2 (log k′ (PBD-TiO2)) in a methanol-water (80:20, v/v) mobile versus the solutes' four interaction descriptors, the McGowan characteristic molar volume (Vx), dipolarity/polarizability (Π2*), effective or overall hydrogen bond donor acidity (Σα2 H ) and hydrogen bond acceptor basicity (Σβ2 H ) are analyzed by multiple regression analysis and compared to conventional bonded reversed stationary phase. We find that PBD-TiO2 is very similar to conventional bonded reversed stationary phase. The descriptors, Vx, π2* and Σβ2 H are the most important parameters governing the retention, as they represent more than 96.62% of the log k′ variation. Finally, we come to the conclusion that the retention of PBD-TiO2 is a partition mechanism." @default.
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- W2083009718 date "2000-04-26" @default.
- W2083009718 modified "2023-10-16" @default.
- W2083009718 title "RETENTION BEHAVIORS OF POLYBUTADIENE-COATED TITANIA AND COMPARISON TO BONDED PHASE ON LINEAR SOLVATION ENERGY RELATIONSHIPS" @default.
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- W2083009718 doi "https://doi.org/10.1081/jlc-100100406" @default.
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