Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083079286> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2083079286 endingPage "459" @default.
- W2083079286 startingPage "456" @default.
- W2083079286 abstract "The direct photolysis at 1849 Å and the mercury-photosensitized reaction at 2537 Å of cis-2-butene have been studied in the gas phase at room temperature. It may be considered that the excited singlet state of cis-2-butene is formed in the former, and that the excited triplet state of cis-2-butene is formed in the latter. trans-2-Butene is predominantly produced in the latter, while the decomposition products (e. g., hydrogen, methane, ethane, ethylene, propylene, etc.) predominate in the former. The rates of the formation of all the products are pressure-independent in the former, while in the latter those of all products except trans-2-butene decrease rapidly with an increase in the initial pressure. The rate of trans-2-hutene formation in the latter, however, increases gradually with an increase in the initial pressure until it becomes constant above 100 mmHg. By comparing the pressure-dependence and the product-distribution of these two reactions with the results of the radiolysis of liquid cis-2-butene, one may conclude that the excited triplet state of cis-2-butene contributes chiefly to the formation of trans-2-butene in the radiolysis, while the excited singlet state of cis-2-butene contributes chiefly to the decomposition products." @default.
- W2083079286 created "2016-06-24" @default.
- W2083079286 creator A5064189027 @default.
- W2083079286 creator A5076139673 @default.
- W2083079286 date "1966-03-01" @default.
- W2083079286 modified "2023-10-18" @default.
- W2083079286 title "The Photolysis ofcis-2-Butene and Its Implications for Radiation Chemistry" @default.
- W2083079286 cites W1594686942 @default.
- W2083079286 cites W1964671364 @default.
- W2083079286 cites W1995174290 @default.
- W2083079286 cites W2004961307 @default.
- W2083079286 cites W2013034835 @default.
- W2083079286 cites W2068518667 @default.
- W2083079286 cites W2093790119 @default.
- W2083079286 doi "https://doi.org/10.1246/bcsj.39.456" @default.
- W2083079286 hasPublicationYear "1966" @default.
- W2083079286 type Work @default.
- W2083079286 sameAs 2083079286 @default.
- W2083079286 citedByCount "5" @default.
- W2083079286 crossrefType "journal-article" @default.
- W2083079286 hasAuthorship W2083079286A5064189027 @default.
- W2083079286 hasAuthorship W2083079286A5076139673 @default.
- W2083079286 hasBestOaLocation W20830792861 @default.
- W2083079286 hasConcept C121332964 @default.
- W2083079286 hasConcept C139066938 @default.
- W2083079286 hasConcept C161790260 @default.
- W2083079286 hasConcept C178790620 @default.
- W2083079286 hasConcept C181500209 @default.
- W2083079286 hasConcept C185544564 @default.
- W2083079286 hasConcept C185592680 @default.
- W2083079286 hasConcept C2776164856 @default.
- W2083079286 hasConcept C2777765387 @default.
- W2083079286 hasConcept C2778597550 @default.
- W2083079286 hasConcept C2778601030 @default.
- W2083079286 hasConcept C32909587 @default.
- W2083079286 hasConcept C33062035 @default.
- W2083079286 hasConcept C54582936 @default.
- W2083079286 hasConcept C66887884 @default.
- W2083079286 hasConcept C75473681 @default.
- W2083079286 hasConcept C76766466 @default.
- W2083079286 hasConceptScore W2083079286C121332964 @default.
- W2083079286 hasConceptScore W2083079286C139066938 @default.
- W2083079286 hasConceptScore W2083079286C161790260 @default.
- W2083079286 hasConceptScore W2083079286C178790620 @default.
- W2083079286 hasConceptScore W2083079286C181500209 @default.
- W2083079286 hasConceptScore W2083079286C185544564 @default.
- W2083079286 hasConceptScore W2083079286C185592680 @default.
- W2083079286 hasConceptScore W2083079286C2776164856 @default.
- W2083079286 hasConceptScore W2083079286C2777765387 @default.
- W2083079286 hasConceptScore W2083079286C2778597550 @default.
- W2083079286 hasConceptScore W2083079286C2778601030 @default.
- W2083079286 hasConceptScore W2083079286C32909587 @default.
- W2083079286 hasConceptScore W2083079286C33062035 @default.
- W2083079286 hasConceptScore W2083079286C54582936 @default.
- W2083079286 hasConceptScore W2083079286C66887884 @default.
- W2083079286 hasConceptScore W2083079286C75473681 @default.
- W2083079286 hasConceptScore W2083079286C76766466 @default.
- W2083079286 hasIssue "3" @default.
- W2083079286 hasLocation W20830792861 @default.
- W2083079286 hasOpenAccess W2083079286 @default.
- W2083079286 hasPrimaryLocation W20830792861 @default.
- W2083079286 hasRelatedWork W1966677725 @default.
- W2083079286 hasRelatedWork W1967801022 @default.
- W2083079286 hasRelatedWork W2019940683 @default.
- W2083079286 hasRelatedWork W2023896633 @default.
- W2083079286 hasRelatedWork W2055439684 @default.
- W2083079286 hasRelatedWork W2083079286 @default.
- W2083079286 hasRelatedWork W2085081709 @default.
- W2083079286 hasRelatedWork W2093025165 @default.
- W2083079286 hasRelatedWork W2104099569 @default.
- W2083079286 hasRelatedWork W2118781715 @default.
- W2083079286 hasVolume "39" @default.
- W2083079286 isParatext "false" @default.
- W2083079286 isRetracted "false" @default.
- W2083079286 magId "2083079286" @default.
- W2083079286 workType "article" @default.