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- W2083094949 abstract "Mössbauer spectra of the polycrystalline form of the intermediate-spin complex perchlorato (meso-tetraphenylporphinato) iron (III) 0.5 m-xylene have been observed at a variety of temperatures in high external fields. Analysis of the resulting spectra yields a positive electric field gradient interaction with quadrupole splitting ΔE=3.5 mm/s (4.2 K) and 2.79 mm/s (300 K). At low temperature an external magnetic field induces negligible internal field along the symmetry axis. In the transverse direction it gives rise to a temperature-dependent negative internal field of about 23 T (4.2 K). The data have been analyzed in terms of a S=3/2 spin-Hamiltonian and the five spin-Hamiltonian parameters required to characterize the spectra at all temperatures and fields were D=8.0 cm−1, λ=0.15, Ax=1.273, Ay=1.119, Az=−0.164 mm/s (excited state)." @default.
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- W2083094949 date "1979-08-15" @default.
- W2083094949 modified "2023-09-27" @default.
- W2083094949 title "Mössbauer effect study of the magnetic properties of the intermediate-spin complex perchlorato (<i>m</i> <i>e</i> <i>s</i> <i>o</i>-tetraphenylporphinato ) iron (III)" @default.
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- W2083094949 doi "https://doi.org/10.1063/1.438534" @default.
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