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- W2083142495 abstract "Abstract The preparation and cyclopolymerization of dipropargyl sulfoxide were studied. The polymerization of dipropargyl sulfoxide was carried out by various transition metal catalysts. WCl 6 –EtAlCl 2 , MoCl 5 , and PdCl 2 catalyst systems were very effective. The resulting poly(dipropargyl sulfoxide) structures were characterized by NMR ( 1 H and 13 C), IR, and elemental analysis to have conjugated polyene units. Poly(dipropargyl sulfoxide) prepared by PdCl 2 was mostly soluble in organic solvents such as DMF and DMSO. Thermal and oxidative properties of poly(dipropargyl sulfoxide) were also studied. The electrical conductivity of iodine‐doped poly(dipropargyl sulfoxide) was 5.2 × 10 −2 Ω −1 cm −1 . Comparisons of poly(dipropargyl sulfoxide) properties with other similar polymers from dipropargyl sulfur derivatives such as dipropargyl sulfide and dipropargyl sulfone were also carried out. © 1993 John Wiley & Sons, Inc." @default.
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- W2083142495 date "1993-02-01" @default.
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- W2083142495 title "Synthesis and properties of poly(dipropargyl sulfoxide)" @default.
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- W2083142495 doi "https://doi.org/10.1002/pola.1993.080310206" @default.
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