Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083148097> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2083148097 endingPage "140" @default.
- W2083148097 startingPage "131" @default.
- W2083148097 abstract "The electrochemistry of xanthine oxidase has been examined at glassy carbon and mercury electrodes. No response is observed at glassy carbon unless denaturation of the enzyme has occurred in which case a surface-confined chemically reversible process FAD + 2 H+ + 2 e− ⇄ FADH2 is observed (FAD = flavin adenine dinucleotide). In contrast, at mercury electrodes, processes associated with FAD and with enzyme-bound mercuric cysteinate, cysteine and cystine groups are observed, even under conditions where no free FAD is detected at a glassy carbon electrode. Study of these processes as a function of pH, after interaction with Hg2+ and after conversion of xanthine oxidase to xanthine dehydrogenase, allows a self-consistent reaction scheme to be proposed. Interestingly, at the mercury electrode, no potential is available at which a redox process does not occur and consequently, denaturation of the protein takes place at the electrode surface at all potentials. No molybdenum- or Fe2S2-based electrochemistry was detected." @default.
- W2083148097 created "2016-06-24" @default.
- W2083148097 creator A5025413246 @default.
- W2083148097 creator A5045117180 @default.
- W2083148097 creator A5066751558 @default.
- W2083148097 date "1991-08-01" @default.
- W2083148097 modified "2023-09-27" @default.
- W2083148097 title "Electrochemistry of xanthine oxidase at glassy carbon and mercury electrodes" @default.
- W2083148097 cites W1596401706 @default.
- W2083148097 cites W1747820606 @default.
- W2083148097 cites W1974424679 @default.
- W2083148097 cites W1977861573 @default.
- W2083148097 cites W2006958782 @default.
- W2083148097 cites W2017458184 @default.
- W2083148097 cites W2018224785 @default.
- W2083148097 cites W2040295479 @default.
- W2083148097 cites W2060017397 @default.
- W2083148097 cites W2064795472 @default.
- W2083148097 cites W2088251656 @default.
- W2083148097 cites W2141942536 @default.
- W2083148097 doi "https://doi.org/10.1016/0022-0728(91)85148-i" @default.
- W2083148097 hasPublicationYear "1991" @default.
- W2083148097 type Work @default.
- W2083148097 sameAs 2083148097 @default.
- W2083148097 citedByCount "37" @default.
- W2083148097 countsByYear W20831480972012 @default.
- W2083148097 countsByYear W20831480972013 @default.
- W2083148097 countsByYear W20831480972015 @default.
- W2083148097 countsByYear W20831480972016 @default.
- W2083148097 countsByYear W20831480972017 @default.
- W2083148097 crossrefType "journal-article" @default.
- W2083148097 hasAuthorship W2083148097A5025413246 @default.
- W2083148097 hasAuthorship W2083148097A5045117180 @default.
- W2083148097 hasAuthorship W2083148097A5066751558 @default.
- W2083148097 hasConcept C147789679 @default.
- W2083148097 hasConcept C17525397 @default.
- W2083148097 hasConcept C179104552 @default.
- W2083148097 hasConcept C181199279 @default.
- W2083148097 hasConcept C185592680 @default.
- W2083148097 hasConcept C192562407 @default.
- W2083148097 hasConcept C199360897 @default.
- W2083148097 hasConcept C2776422427 @default.
- W2083148097 hasConcept C2777777548 @default.
- W2083148097 hasConcept C2777869211 @default.
- W2083148097 hasConcept C2778102346 @default.
- W2083148097 hasConcept C41008148 @default.
- W2083148097 hasConcept C52859227 @default.
- W2083148097 hasConcept C55493867 @default.
- W2083148097 hasConceptScore W2083148097C147789679 @default.
- W2083148097 hasConceptScore W2083148097C17525397 @default.
- W2083148097 hasConceptScore W2083148097C179104552 @default.
- W2083148097 hasConceptScore W2083148097C181199279 @default.
- W2083148097 hasConceptScore W2083148097C185592680 @default.
- W2083148097 hasConceptScore W2083148097C192562407 @default.
- W2083148097 hasConceptScore W2083148097C199360897 @default.
- W2083148097 hasConceptScore W2083148097C2776422427 @default.
- W2083148097 hasConceptScore W2083148097C2777777548 @default.
- W2083148097 hasConceptScore W2083148097C2777869211 @default.
- W2083148097 hasConceptScore W2083148097C2778102346 @default.
- W2083148097 hasConceptScore W2083148097C41008148 @default.
- W2083148097 hasConceptScore W2083148097C52859227 @default.
- W2083148097 hasConceptScore W2083148097C55493867 @default.
- W2083148097 hasIssue "1-2" @default.
- W2083148097 hasLocation W20831480971 @default.
- W2083148097 hasOpenAccess W2083148097 @default.
- W2083148097 hasPrimaryLocation W20831480971 @default.
- W2083148097 hasRelatedWork W1969668412 @default.
- W2083148097 hasRelatedWork W1978222176 @default.
- W2083148097 hasRelatedWork W1978981331 @default.
- W2083148097 hasRelatedWork W2040299276 @default.
- W2083148097 hasRelatedWork W2080624694 @default.
- W2083148097 hasRelatedWork W2086723743 @default.
- W2083148097 hasRelatedWork W2365935196 @default.
- W2083148097 hasRelatedWork W2428993389 @default.
- W2083148097 hasRelatedWork W2510617744 @default.
- W2083148097 hasRelatedWork W2951903765 @default.
- W2083148097 hasVolume "312" @default.
- W2083148097 isParatext "false" @default.
- W2083148097 isRetracted "false" @default.
- W2083148097 magId "2083148097" @default.
- W2083148097 workType "article" @default.