FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083151427> ?p ?o ?g. }

• W2083151427 endingPage "1308" @default.
• W2083151427 startingPage "1304" @default.
• W2083151427 abstract "A high density polyethylene was spin-labelled by the reaction of the alkyl type free radical, with 2,4,6-tri-t-butyl nitrosobenzene as a spin-trapping reagent. Extrema separations and line widths of e.s.r. spectrum of nitroxide free radicals were obtained and used in order to calculate correlation times of the motion of the label in a wide temperature range. Spin rotational frequencies of free radicals were compared with the correlation frequencies obtained from a relaxation map which revealed α-, β- and γ-relaxation processes in solid polyethylene. It was concluded that the motional narrowing of the line width in the high temperature region 283–343 K with an activation energy of 9.2 kcal/mol, was caused by the β-relaxation process, which is normally attributed to the large scale segmental motion over the whole molecular chain in the amorphous phase. The decrease of the extrema separation in the higher temperature region 353–383 K was conisdered due to the same mechanism of the relaxation observed in the 283–343 K region in the case of the line width study. These e.s.r. techniques gave lower activation energies of β-relaxation process than those obtained by dielectric and mechanical relaxation measurements. This discrepancy was interpreted in terms of the distribution of relaxation times. The relaxation spectrum for the β-process was discussed based on the Miyake equation." @default.
• W2083151427 created "2016-06-24" @default.
• W2083151427 creator A5003185802 @default.
• W2083151427 creator A5036086465 @default.
• W2083151427 creator A5052298066 @default.
• W2083151427 date "1980-11-01" @default.
• W2083151427 modified "2023-09-27" @default.
• W2083151427 title "Relaxation processes and mobility of spin labelled polyethylene" @default.
• W2083151427 cites W1561242261 @default.
• W2083151427 cites W1965345367 @default.
• W2083151427 cites W1982147546 @default.
• W2083151427 cites W1988898278 @default.
• W2083151427 cites W2003156958 @default.
• W2083151427 cites W2020832422 @default.
• W2083151427 cites W2032181395 @default.
• W2083151427 cites W2038187368 @default.
• W2083151427 cites W2039522698 @default.
• W2083151427 cites W2045639663 @default.
• W2083151427 cites W2057605182 @default.
• W2083151427 cites W2090183904 @default.
• W2083151427 doi "https://doi.org/10.1016/0032-3861(80)90198-6" @default.
• W2083151427 hasPublicationYear "1980" @default.
• W2083151427 type Work @default.
• W2083151427 sameAs 2083151427 @default.
• W2083151427 citedByCount "5" @default.
• W2083151427 countsByYear W20831514272013 @default.
• W2083151427 crossrefType "journal-article" @default.
• W2083151427 hasAuthorship W2083151427A5003185802 @default.
• W2083151427 hasAuthorship W2083151427A5036086465 @default.
• W2083151427 hasAuthorship W2083151427A5052298066 @default.
• W2083151427 hasConcept C113196181 @default.
• W2083151427 hasConcept C121332964 @default.
• W2083151427 hasConcept C1276947 @default.
• W2083151427 hasConcept C133386390 @default.
• W2083151427 hasConcept C147789679 @default.
• W2083151427 hasConcept C15744967 @default.
• W2083151427 hasConcept C175249596 @default.
• W2083151427 hasConcept C178790620 @default.
• W2083151427 hasConcept C185592680 @default.
• W2083151427 hasConcept C192562407 @default.
• W2083151427 hasConcept C2776029896 @default.
• W2083151427 hasConcept C2777094241 @default.
• W2083151427 hasConcept C2778981401 @default.
• W2083151427 hasConcept C2779751980 @default.
• W2083151427 hasConcept C36703968 @default.
• W2083151427 hasConcept C39353612 @default.
• W2083151427 hasConcept C41999313 @default.
• W2083151427 hasConcept C46141821 @default.
• W2083151427 hasConcept C4839761 @default.
• W2083151427 hasConcept C49040817 @default.
• W2083151427 hasConcept C56052488 @default.
• W2083151427 hasConcept C77805123 @default.
• W2083151427 hasConcept C8010536 @default.
• W2083151427 hasConcept C95121573 @default.
• W2083151427 hasConcept C97355855 @default.
• W2083151427 hasConceptScore W2083151427C113196181 @default.
• W2083151427 hasConceptScore W2083151427C121332964 @default.
• W2083151427 hasConceptScore W2083151427C1276947 @default.
• W2083151427 hasConceptScore W2083151427C133386390 @default.
• W2083151427 hasConceptScore W2083151427C147789679 @default.
• W2083151427 hasConceptScore W2083151427C15744967 @default.
• W2083151427 hasConceptScore W2083151427C175249596 @default.
• W2083151427 hasConceptScore W2083151427C178790620 @default.
• W2083151427 hasConceptScore W2083151427C185592680 @default.
• W2083151427 hasConceptScore W2083151427C192562407 @default.
• W2083151427 hasConceptScore W2083151427C2776029896 @default.
• W2083151427 hasConceptScore W2083151427C2777094241 @default.
• W2083151427 hasConceptScore W2083151427C2778981401 @default.
• W2083151427 hasConceptScore W2083151427C2779751980 @default.
• W2083151427 hasConceptScore W2083151427C36703968 @default.
• W2083151427 hasConceptScore W2083151427C39353612 @default.
• W2083151427 hasConceptScore W2083151427C41999313 @default.
• W2083151427 hasConceptScore W2083151427C46141821 @default.
• W2083151427 hasConceptScore W2083151427C4839761 @default.
• W2083151427 hasConceptScore W2083151427C49040817 @default.
• W2083151427 hasConceptScore W2083151427C56052488 @default.
• W2083151427 hasConceptScore W2083151427C77805123 @default.
• W2083151427 hasConceptScore W2083151427C8010536 @default.
• W2083151427 hasConceptScore W2083151427C95121573 @default.
• W2083151427 hasConceptScore W2083151427C97355855 @default.
• W2083151427 hasIssue "11" @default.
• W2083151427 hasLocation W20831514271 @default.
• W2083151427 hasOpenAccess W2083151427 @default.
• W2083151427 hasPrimaryLocation W20831514271 @default.
• W2083151427 hasRelatedWork W1978161873 @default.
• W2083151427 hasRelatedWork W1980779261 @default.
• W2083151427 hasRelatedWork W1990487057 @default.
• W2083151427 hasRelatedWork W1991904866 @default.
• W2083151427 hasRelatedWork W2007115570 @default.
• W2083151427 hasRelatedWork W2019334827 @default.
• W2083151427 hasRelatedWork W2083151427 @default.
• W2083151427 hasRelatedWork W2090197589 @default.
• W2083151427 hasRelatedWork W2091367519 @default.
• W2083151427 hasRelatedWork W2189262842 @default.
• W2083151427 hasVolume "21" @default.
• W2083151427 isParatext "false" @default.
• W2083151427 isRetracted "false" @default.
• W2083151427 magId "2083151427" @default.

• next