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- W2083162894 abstract "We report the deliberate use of molecular shape as a structural tool for generating homochiral photoreactive crystalline materials. Building on the crystal packing tendencies of amino acid quasiracemates to form near inversion related motifs, L-leucine and D-methionine were decorated with sulfonamidecinnamic acid groups. When co-crystallized, the ‘fish hook’ shaped components organize into supramolecular dimers with favorable olefin⋯olefin spacing (3.71 and 4.09 Å). UV exposed samples were processed as single-crystal-to-single-crystal transformations and showed quantitative conversion to the expected enantiopure photodimerization product. Similar crystal motifs and reaction outcomes were achieved using the racemic counterparts suggesting the importance of best-fit scenarios directed by the complementary features of molecular shape and non-bonded contacts." @default.
- W2083162894 created "2016-06-24" @default.
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- W2083162894 date "2014-01-01" @default.
- W2083162894 modified "2023-10-16" @default.
- W2083162894 title "Chiral transmission to crystal photodimerizations of leucine–methionine quasiracemic assemblies" @default.
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- W2083162894 doi "https://doi.org/10.1039/c3ra47270a" @default.
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