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- W2083183458 abstract "Abstract It has been predicted by Pons and Dantzer that temperature gradients due to the released enthalpy of H absorption-desorption will generate macroscopic inhomogeneities of the α β phase proportions in metal hydrides. We used in situ X-ray diffraction and in situ neutron diffraction respectively to study the growth of β-LaNi5H at the free surface, and β-LaNi5D in the bulk of powdered samples. It was found that a macroscopic compositional inhomogeneity does occur, and can be so severe that the free surface of the sample remains pure α phase while the bulk of the sample is rich in β phase." @default.
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- W2083183458 date "1995-01-01" @default.
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- W2083183458 title "Stability of the hydrogen absorption and desorption plateaux in LaNi5H Part 3: experimental observations of compositional inhomogeneities due to temperature gradients" @default.
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- W2083183458 doi "https://doi.org/10.1016/0925-8388(94)01311-5" @default.
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