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• W2083193059 abstract "The Ag doped Hg(Tl):1223 films have been synthesised by annealing Ba2Ca2.2Cu3.3Oz(Agy); y= 0, 0.25, 0.5, 0.75, 1.0 precursors deposited by spray pyrolysis on single crystal MgO and ZrO2 substrates, in controlled Hg-Tl vapour ambient in an evacuated sealed quartz tube at 860°C for 720 minutes. The transition temperature (Tc), dc transport critical current density (Jc) and microstructure of the films have been found sensitive to Ag content. The microstructural details as revealed through scanning electron microscopy exhibit the curious characteristics of the existence of spiral like growth feature which is found to deteriorate with increasing Ag concentration. The maximum Tc = 126 K of the as synthesized Ag doped film with Ag = 0.50 is nearly the same as the Tc = 127 K of oxygen annealed Ag-free films, suggesting in itu oxygenation. The transition temperature has been found to decrease for higher Ag contents (0.50 < y < 1.00). The Jc has been observed to decrease steadily with increase in silver content, being highest (7.2 x 104 A/cm2, 20 K) in Ag-free case. This decrease in Jc has been accounted for in term of formation of Ag(Hg) amalgam due to the reaction of Ag with Hg already present in the grain boundary region." @default.
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• W2083193059 date "1997-01-01" @default.
• W2083193059 modified "2023-10-14" @default.
• W2083193059 title "Effect of Ag doping on the transition temperature and critical current density of Hg1−xTlxBa2Ca2Cu3O8+δ films fabricated through spray pyrolysis" @default.
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• W2083193059 doi "https://doi.org/10.1016/s0921-4534(96)00650-8" @default.
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