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• W2083212929 abstract "The catalytic chain transfer polymerization of CO2-expanded butyl methacrylate and styrene is reported. Experimentally determined values of the chain transfer constant for CO2-expanded butyl methacrylate are presented at 50 and 60 °C and in the range of pressure from 0.1 to 6 MPa, using a cobaloxime complex as the chain transfer catalyst. Similar data are reported for CO2-expanded styrene at 50 °C. The chain transfer constants for both expanded monomers are significantly higher than those obtained in the bulk monomers. It is demonstrated that a linear relationship exists between the chain transfer rate coefficient and the inverse of viscosity. These results provide significant evidence that the rate-determining step in the chain transfer process is diffusion-controlled." @default.
• W2083212929 created "2016-06-24" @default.
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• W2083212929 date "2006-11-17" @default.
• W2083212929 modified "2023-10-17" @default.
• W2083212929 title "Effect of Bulk Viscosity on the Catalytic Chain Transfer Polymerization of CO₂-Expanded Butyl Methacrylate and Styrene" @default.
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• W2083212929 doi "https://doi.org/10.1021/ma061370w" @default.
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