Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083215212> ?p ?o ?g. }
- W2083215212 endingPage "217" @default.
- W2083215212 startingPage "203" @default.
- W2083215212 abstract "The industrial production of latexes has grown from the first poly(butadiene-co-styrene) produced in the U.S. for synthetic rubber and the first poly(vinyl acetate) produced in Germany for adhesives to many different polymer families produced for a wide variety of applications. Both conventional (oil-in-water) and inverse (water-in-oil) emulsion polymerization comprise the emulsification of an immiscible monomer in a continuous medium, followed by polymerization with a free radical initiator, to give a colloidal sol of submicroscopic polymer particles smaller by an order of magnitude than the original emulsion droplets. Both processes give “emulsion polymerization kinetics,” i.e., a proportionality of both polymerization rate and number-average degree of polymerization to the number of particles, instead of the inverse relationship between these two parameters observed for mass, solution, and suspension polymerization. The emulsion polymerization process can be divided into particle nucleation and particle growth stages, and it can be carried out using batch, semi-continuous, or continuous processes. Seeded emulsion polymerization can be used to obviate the particle nucleation stage in all three processes. The mechanisms proposed for initiation of emulsion polymerization can be divided into four categories, according to the locus of particle initiation: 1) monomer-swollen emulsifier micelles; 2) adsorbed emulsifier layer; 3) aqueous phase: 4) monomer emulsion droplets. Three generations of latex development are defined, according to the emulsifiers used: 1) conventional emulsifiers; 2) functional monomers; 3) polymeric emulsifiers. The formation of coagulum (polymer recovered from the latex in a form other than stable latex) during emulsion polymerization is attributed to two causes: 1) a failure of the colloidal stability of the latex; 2) polymerization by a different mechanism, e.g., mass (monomer layer), surface (walls, roof, agitator shaft), vapor (atmosphere). The failure of the colloidal stability is attributed to diffusion-controlled, agitation-induced, or surface flocculation of the particles, according to the agitation rate (flow Reynolds numbers) and the power consumption (high Reynolds numbers)." @default.
- W2083215212 created "2016-06-24" @default.
- W2083215212 creator A5000990064 @default.
- W2083215212 date "1993-01-01" @default.
- W2083215212 modified "2023-10-14" @default.
- W2083215212 title "Recent advances in the preparation of latexes" @default.
- W2083215212 cites W1486538174 @default.
- W2083215212 cites W1512067770 @default.
- W2083215212 cites W1522231902 @default.
- W2083215212 cites W1591256505 @default.
- W2083215212 cites W1659688442 @default.
- W2083215212 cites W1965128757 @default.
- W2083215212 cites W1977031615 @default.
- W2083215212 cites W2011381315 @default.
- W2083215212 cites W2013360083 @default.
- W2083215212 cites W2016180508 @default.
- W2083215212 cites W2031285938 @default.
- W2083215212 cites W2038584355 @default.
- W2083215212 cites W2040941529 @default.
- W2083215212 cites W2041424097 @default.
- W2083215212 cites W204389921 @default.
- W2083215212 cites W2058054848 @default.
- W2083215212 cites W2067779117 @default.
- W2083215212 cites W2111213852 @default.
- W2083215212 cites W2116244330 @default.
- W2083215212 cites W2123419179 @default.
- W2083215212 cites W2166779694 @default.
- W2083215212 cites W2312841434 @default.
- W2083215212 cites W2313766755 @default.
- W2083215212 cites W2319950578 @default.
- W2083215212 cites W2328520484 @default.
- W2083215212 cites W2484265684 @default.
- W2083215212 cites W2502251801 @default.
- W2083215212 cites W2504829847 @default.
- W2083215212 cites W2896035102 @default.
- W2083215212 cites W3022231041 @default.
- W2083215212 cites W3158159059 @default.
- W2083215212 doi "https://doi.org/10.1016/0009-2509(93)80009-f" @default.
- W2083215212 hasPublicationYear "1993" @default.
- W2083215212 type Work @default.
- W2083215212 sameAs 2083215212 @default.
- W2083215212 citedByCount "30" @default.
- W2083215212 countsByYear W20832152122012 @default.
- W2083215212 countsByYear W20832152122013 @default.
- W2083215212 countsByYear W20832152122014 @default.
- W2083215212 countsByYear W20832152122015 @default.
- W2083215212 countsByYear W20832152122017 @default.
- W2083215212 countsByYear W20832152122018 @default.
- W2083215212 crossrefType "journal-article" @default.
- W2083215212 hasAuthorship W2083215212A5000990064 @default.
- W2083215212 hasConcept C111368507 @default.
- W2083215212 hasConcept C111998727 @default.
- W2083215212 hasConcept C127313418 @default.
- W2083215212 hasConcept C127413603 @default.
- W2083215212 hasConcept C166940927 @default.
- W2083215212 hasConcept C178790620 @default.
- W2083215212 hasConcept C185592680 @default.
- W2083215212 hasConcept C188027245 @default.
- W2083215212 hasConcept C192562407 @default.
- W2083215212 hasConcept C199002037 @default.
- W2083215212 hasConcept C2778123984 @default.
- W2083215212 hasConcept C2778517922 @default.
- W2083215212 hasConcept C42360764 @default.
- W2083215212 hasConcept C44228677 @default.
- W2083215212 hasConcept C521977710 @default.
- W2083215212 hasConcept C90958600 @default.
- W2083215212 hasConceptScore W2083215212C111368507 @default.
- W2083215212 hasConceptScore W2083215212C111998727 @default.
- W2083215212 hasConceptScore W2083215212C127313418 @default.
- W2083215212 hasConceptScore W2083215212C127413603 @default.
- W2083215212 hasConceptScore W2083215212C166940927 @default.
- W2083215212 hasConceptScore W2083215212C178790620 @default.
- W2083215212 hasConceptScore W2083215212C185592680 @default.
- W2083215212 hasConceptScore W2083215212C188027245 @default.
- W2083215212 hasConceptScore W2083215212C192562407 @default.
- W2083215212 hasConceptScore W2083215212C199002037 @default.
- W2083215212 hasConceptScore W2083215212C2778123984 @default.
- W2083215212 hasConceptScore W2083215212C2778517922 @default.
- W2083215212 hasConceptScore W2083215212C42360764 @default.
- W2083215212 hasConceptScore W2083215212C44228677 @default.
- W2083215212 hasConceptScore W2083215212C521977710 @default.
- W2083215212 hasConceptScore W2083215212C90958600 @default.
- W2083215212 hasIssue "2" @default.
- W2083215212 hasLocation W20832152121 @default.
- W2083215212 hasOpenAccess W2083215212 @default.
- W2083215212 hasPrimaryLocation W20832152121 @default.
- W2083215212 hasRelatedWork W2088868204 @default.
- W2083215212 hasRelatedWork W2355128037 @default.
- W2083215212 hasRelatedWork W2357346518 @default.
- W2083215212 hasRelatedWork W2360796286 @default.
- W2083215212 hasRelatedWork W2366594549 @default.
- W2083215212 hasRelatedWork W2376037411 @default.
- W2083215212 hasRelatedWork W2376673914 @default.
- W2083215212 hasRelatedWork W2383570223 @default.
- W2083215212 hasRelatedWork W2390480717 @default.
- W2083215212 hasRelatedWork W2393068811 @default.
- W2083215212 hasVolume "48" @default.
- W2083215212 isParatext "false" @default.