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• W2083231505 abstract "T,x-Phasendiagramme der Systeme ThI4SnI2, ThI4PbI2, ThI4CaI2 und ThI4SrI2 wurden mit thermoanalytischen und röntgenographischen Methoden erstellt. Als ternäre Phasen existieren nur die 1:1 Verbindungen. AcMX6 Verbindungen (Ac: Th, U; M: Ca, Sr, Ba, Eu, Ge, Sn, Pb; X: Br, I) wurden synthetisiert und strukturell untersucht. Sie treten in Abhängigkeit von der Temperatur bzw. der Ac/M Kombination in 4 Strukturtypen auf. Die Strukturen von γ-ThSnI6 und β-ThSnI6 konnten stellvertretend für eine ganze Reihe isotyper Verbindungen mit Einkristallmethoden aufgeklärt werden. Formation of Compounds in the Quasi-binary Systems AcX4MX2 (Ac = Th, U; M = Ca, Sr, Ba, Eu, Ge, Sn, Pb; X = Br, I) T,x-phase diagrams of the systems ThI4SnI2, ThI4PbI2, ThI4CaI2, and ThI4SrI2 were established using thermoanalysis and x-ray methods. The only ternary compounds have a 1:1 composition. Further AcMX6 compounds (Ac: Th, U; M: Ca, Sr, Ba, Eu, Ge, Sn, Pb; X: Br, I) were synthesized and their structures investigated. Four structure types are found depending on the temperature and the Ac/M combinations. The structures of γ-ThSnI6 and β-ThSnI6 were determined with single crystal methods as representatives of a whole series of isotypic compounds." @default.
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• W2083231505 date "1993-02-01" @default.
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• W2083231505 title "Verbindungsbildung in den quasi-bin�ren Systemen AcX4?MX2 (Ac = Th, U; M = Ca, Sr, Ba, Eu, Ge, Sn, Pb; X = Br, I)" @default.
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• W2083231505 doi "https://doi.org/10.1002/zaac.19936190202" @default.
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