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• W2083245968 abstract "The process of reactive diffusion of Ni in thin films is studied during the low temperature (250°C<300°C) growth of Ni2Si on Si(100) and Si(111) substrates. The silicide on the Si(111) substrates presents textured structures which probably involves mainly low-angle (<15°) grain boundaries, whereas the grains of the silicide on the Si(100) substrates do not show texture correspondingly presenting a random predominantly high-angle grain boundary distribution. Assuming Ni grain boundary diffusion being the dominant limiting process of the solid-state reaction, the corresponding grain boundary reactive diffusion coefficient is determined from the kinetics of the silicide formation. It is observed that the coefficient belonging to low-angle boundaries is smaller than that measured in randomly distributed high-angle boundaries and they are determined to be Dgb=1.74×10−2 exp (−1.22/kT) cm2/s and Dgb=7.45×10−1 exp(−1.35/kT) cm2/s, respectively. The results indicate similarity between normal and reactive diffusion processes." @default.
• W2083245968 created "2016-06-24" @default.
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• W2083245968 date "1999-01-01" @default.
• W2083245968 modified "2023-10-14" @default.
• W2083245968 title "Grain boundary reactive diffusion during Ni2Si formation in thin films and its dependence on the grain boundary angle" @default.
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• W2083245968 doi "https://doi.org/10.1016/s0169-4332(98)00475-9" @default.
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