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- W2083256987 abstract "L'oxydation électrocatalytique du propanediol-1,2 et du propanediol-1,3 a été étudiée comparativement sur le platine lisse en milieu H2SO4 0,5 M, afin de rechercher un effet d'isomérie sur la réactivitéélectrochimique de la molécule. Le comportement de l'isomère 1,3 est voisin de celui d'un alcool primaire, tandis que l'isomère 1,2 qui a un comportement très différent de celui d'un alcool secondaire, se rapproche de l'éthylène-glycol. The electrooxidation of both 1,2- and 1,3-propanediol has been investigatted on a smooth platinum electrode in 0.5 M H2SO4 by cyclic voltammetry. The electrochemical reactivity of both isomers is quite different, thus displaying an isomeric effect. The behaviour of the 1,3 isomer is close to that of primary alcohols, whereas the behaviour of the 1,2 isomer, which is markedly different from that of secondary alcohols, looks like that of ethylene-glycol." @default.
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- W2083256987 date "1985-10-01" @default.
- W2083256987 modified "2023-10-18" @default.
- W2083256987 title "Oxydation electrocatalytique des propanediols sur le platine en milieu aqueux acide" @default.
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- W2083256987 doi "https://doi.org/10.1016/0013-4686(85)85024-6" @default.
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