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- W2083264015 abstract "1H NMR and CD spectra have shown the creation of chirality centers on thioether sulfur atoms when bound to metal ions in Pd(II) complexes with S-benzyl-L-cysteine and glycyl-S-benzyl-L-cysteine. Two diastereomers are formed with R or S configuration on the sulfur. The 1H NMR and CD spectra as well as the molecular model considerations were used to suggest the absolution configuration of the respective diastereomers in the series of Pd(II) complexes with S-methyl, S-ethyl and S-benzyl-L-cysteine derivatives. The S-substituent was also found to have a critical influence on the absolute configuration of sulfur atom in the studied complexes." @default.
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- W2083264015 date "1983-01-01" @default.
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- W2083264015 title "NMR and CD studies of sulfur chirality center in Pd(II) complexes with S-benzyl-cysteine and glycyl-S-benzyl-L-cysteine" @default.
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- W2083264015 doi "https://doi.org/10.1016/s0020-1693(00)86484-1" @default.
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