Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083275715> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2083275715 endingPage "53" @default.
- W2083275715 startingPage "45" @default.
- W2083275715 abstract "Aqueous solutions of cyanide react with hydrogen peroxide/horseradish peroxidase and form the cyanyl radical, which can be trapped by 2-methyl-2-nitrosopropane (t-nitrosobutane, tNB) at pH 9.8. At lower pH a variety of radical adducts are formed; at higher pH, the main product was the spin adduct of the formamide radical with tNB. The use of deuterated tNB and 15N-labeled potassium cyanide allowed the observation of the very small nitrogen coupling of this radical adduct. Experiments using 3,5-dibromo-4-nitrosobenzenesulfonic acid (DBNBS) as the spin trap yielded only the formamide radical adduct, which was identified by an independent synthesis starting from formamide. Both hydrogen splittings of its amino group could be resolved using deuterated DBNBS as the spin trap." @default.
- W2083275715 created "2016-06-24" @default.
- W2083275715 creator A5015414029 @default.
- W2083275715 creator A5032324284 @default.
- W2083275715 creator A5037507374 @default.
- W2083275715 date "1989-09-01" @default.
- W2083275715 modified "2023-09-25" @default.
- W2083275715 title "Free radical intermediates formed during the oxidation of cyanide by horseradish peroxidase/H2O2 as detected with nitroso spin traps" @default.
- W2083275715 cites W1485390666 @default.
- W2083275715 cites W1516090436 @default.
- W2083275715 cites W1987702709 @default.
- W2083275715 cites W2014195650 @default.
- W2083275715 cites W2014257164 @default.
- W2083275715 cites W2016313124 @default.
- W2083275715 cites W2017712613 @default.
- W2083275715 cites W2026393519 @default.
- W2083275715 cites W2027245649 @default.
- W2083275715 cites W2035187571 @default.
- W2083275715 cites W2041698342 @default.
- W2083275715 cites W2063929278 @default.
- W2083275715 cites W2070652264 @default.
- W2083275715 cites W2074507512 @default.
- W2083275715 cites W2085276728 @default.
- W2083275715 cites W4235018263 @default.
- W2083275715 cites W950616869 @default.
- W2083275715 doi "https://doi.org/10.1016/0162-0134(89)80028-5" @default.
- W2083275715 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/2552012" @default.
- W2083275715 hasPublicationYear "1989" @default.
- W2083275715 type Work @default.
- W2083275715 sameAs 2083275715 @default.
- W2083275715 citedByCount "14" @default.
- W2083275715 countsByYear W20832757152015 @default.
- W2083275715 crossrefType "journal-article" @default.
- W2083275715 hasAuthorship W2083275715A5015414029 @default.
- W2083275715 hasAuthorship W2083275715A5032324284 @default.
- W2083275715 hasAuthorship W2083275715A5037507374 @default.
- W2083275715 hasConcept C108204754 @default.
- W2083275715 hasConcept C139066938 @default.
- W2083275715 hasConcept C178790620 @default.
- W2083275715 hasConcept C179104552 @default.
- W2083275715 hasConcept C181199279 @default.
- W2083275715 hasConcept C184651966 @default.
- W2083275715 hasConcept C185592680 @default.
- W2083275715 hasConcept C2777676563 @default.
- W2083275715 hasConcept C2778270854 @default.
- W2083275715 hasConcept C2778455166 @default.
- W2083275715 hasConcept C2778815226 @default.
- W2083275715 hasConcept C533411734 @default.
- W2083275715 hasConcept C75473681 @default.
- W2083275715 hasConceptScore W2083275715C108204754 @default.
- W2083275715 hasConceptScore W2083275715C139066938 @default.
- W2083275715 hasConceptScore W2083275715C178790620 @default.
- W2083275715 hasConceptScore W2083275715C179104552 @default.
- W2083275715 hasConceptScore W2083275715C181199279 @default.
- W2083275715 hasConceptScore W2083275715C184651966 @default.
- W2083275715 hasConceptScore W2083275715C185592680 @default.
- W2083275715 hasConceptScore W2083275715C2777676563 @default.
- W2083275715 hasConceptScore W2083275715C2778270854 @default.
- W2083275715 hasConceptScore W2083275715C2778455166 @default.
- W2083275715 hasConceptScore W2083275715C2778815226 @default.
- W2083275715 hasConceptScore W2083275715C533411734 @default.
- W2083275715 hasConceptScore W2083275715C75473681 @default.
- W2083275715 hasIssue "1" @default.
- W2083275715 hasLocation W20832757151 @default.
- W2083275715 hasLocation W20832757152 @default.
- W2083275715 hasOpenAccess W2083275715 @default.
- W2083275715 hasPrimaryLocation W20832757151 @default.
- W2083275715 hasRelatedWork W1520525278 @default.
- W2083275715 hasRelatedWork W1964500091 @default.
- W2083275715 hasRelatedWork W2012584566 @default.
- W2083275715 hasRelatedWork W2013440167 @default.
- W2083275715 hasRelatedWork W2058143492 @default.
- W2083275715 hasRelatedWork W2070652264 @default.
- W2083275715 hasRelatedWork W2083275715 @default.
- W2083275715 hasRelatedWork W2382067821 @default.
- W2083275715 hasRelatedWork W2419315897 @default.
- W2083275715 hasRelatedWork W2582746614 @default.
- W2083275715 hasVolume "37" @default.
- W2083275715 isParatext "false" @default.
- W2083275715 isRetracted "false" @default.
- W2083275715 magId "2083275715" @default.
- W2083275715 workType "article" @default.