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- W2083283181 abstract "A chiral 5-deazaflavin 1 with 2-hydroxynaphthyl group at N(3) position of the pyrimidine ring moiety was synthesized. 1 underwent, in the absence of magnesium ion, a “(net) hydride transfer” from BNAH to C(5) almost exclusively on the face where OH group is present. It was also the case with PNPH, and enantioselectivity for PNPH by 1 was higher in the absence of magnesium ion than in its presence. These results indicate that the “diastereotopic face activation” in 1 is operated as well as chiral recognition for PNPH by 1." @default.
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- W2083283181 date "1992-11-01" @default.
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- W2083283181 title "First example of “diastereotopic face activation” and chiral recognition without metal assistance. A novel 5-deazaflavin enzyme model." @default.
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- W2083283181 doi "https://doi.org/10.1016/s0040-4039(00)60865-1" @default.
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