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- W2083287712 abstract "α-Aminobutyramide oxime (6), obtained from α-aminobutyronitrile (5) with hydroxylamine, reacted with esters in the presence of sodium ethoxide to furnish 5-substituted 3-(1-aminopropyl)-1,2,4-oxadiazoles 7. α-(Acylamino)butyramide oximes 8 were formed from the compounds 7 by the action of dilute aqueous sodium hydroxide at ambient temperature. This astonishing reaction presumably proceeds by nucleophilic ring fission. Synthese von α-(Acylamino)butyramidoximen aus 5-substituierten 3-(1-Aminopropan-1-yl)-1,2,4-oxadiazolen: Eine überraschende hydrolytische Umwandlung Die Reaktion von α-Aminobutyramidoxim (6), hergestellt aus α-Aminobutyronitril (5) mit Hydroxylamin, mit Estern in Gegenwart von Natriumethoxid führte zu 5-substituierten 3-(1-Aminopropyl)-1,2,4-oxadiazolen 7. Bei der Reaktion von 7 mit verdünntem wäßrigem Natriumhydroxid bei Raumtemperatur wurden überraschend α-(Acylamino)butyramidoxime (8) gebildet. Diese Umwandlung läuft wahrscheinlich über eine nucleophile Ringspaltung." @default.
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- W2083287712 date "1988-04-01" @default.
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- W2083287712 title "Formation of α‐(acylamino)butyramide oximes from 5‐substituted 3‐(1‐aminopropyl)‐1,2,4‐oxadiazoles: An astonishing hydrolytic transformation" @default.
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- W2083287712 doi "https://doi.org/10.1002/cber.19881210419" @default.
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