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• W2083301831 abstract "Abstract A study on the hydration property of lipid bilayer systems was performed with DSC and X-ray diffraction techniques for two sphingomyelins, a naturally occurring bovine brain sphingomyelin having a heterogeneous acyl chain and a semisynthetic sphingomyelin having the acyl chain of 16 saturated carbons. The number of differently bound interlamellar water molecules was estimated for the two sphingomyelin systems from a deconvolution analysis of the ice-melting DSC curves of varying water content. The estimated limiting, maximum number of freezable interlamellar water molecules for the semisynthetic sphingomyelin system was 5.5 H 2 O per molecule of lipid, which is close to a value (5 H 2 O/lipid) previously reported by us for a system of dipalmitoylphosphatidylcholine. However, for the brain-sphingomyelin system, a limiting hydration for this type of water was not reached even up to the water/lipid molar ratio ∼20. In this accord, the electron density profile analysis of X-ray lamellar diffraction patterns for the brain–SM system showed that the thickness of interlamellar water layer increases in proportion to the amount of added water." @default.
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• W2083301831 date "2004-06-01" @default.
• W2083301831 modified "2023-10-18" @default.
• W2083301831 title "Estimation of interlamellar water molecules in sphingomyelin bilayer systems studied by DSC and X-ray diffraction" @default.
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• W2083301831 doi "https://doi.org/10.1016/j.tca.2003.01.003" @default.
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