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- W2083310369 abstract "Radical oxidations carried out by peroxovanadium complexes, both in CH3CN and in water, are presented. A detailed mechanism for the decomposition of, and benzene hydroxylation by, the peroxocomplex [PicVO(O2)] (Pic = picolinic acid anion) is provided. A very good agreement between calculated and experimental data is observed. Data aimed at establishing a relationship between the nature of peroxovanadium complexes and their reactivity in water are also presented. These include 51V-NMR chemical shifts, Hammett-type and Ramsey-type correlations. Preliminary data obtained from ab initio calculations are also included. A radical chain mechanism, slightly different from that taking place in CH3CN, is presented for the decomposition of peroxovanadium complexes in water. Also in this case a good agreement between calculated and experimental data is found. Both in CH3CN, in water and in CH3CN/water mixtures, the oxidizing agent appears to be the species resulting from the one-electron reduction of the peroxovanadium complexes. Thus, the possible involvement of the HO radical is at least questionable." @default.
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- W2083310369 date "1997-03-01" @default.
- W2083310369 modified "2023-09-26" @default.
- W2083310369 title "Peroxovanadium complexes as radical oxidants in organic solvents and in aqueous solutions" @default.
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- W2083310369 doi "https://doi.org/10.1016/s1381-1169(96)00262-2" @default.
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