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• W2083313989 abstract "Heats of adsorption for nitrogen bases and nucleosides on Sepharose CL-6B, a hydrophobic interaction adsorbent, were collected through flow microcalorimetry in order to ascertain the thermodynamic driving force for adsorption in each case. It was determined that enthalpy changes associated with base stacking self-interactions can contribute significantly to the observed heats of adsorption. Accordingly, the observed heats were the net effect of the adsorbate/adsorbent interactions and the adsorbate stacking self-interactions. Since base stacking proceeds beyond the dimer stage, multi-layer adsorption of these compounds is possible, even at low solution concentrations." @default.
• W2083313989 created "2016-06-24" @default.
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• W2083313989 date "2004-05-01" @default.
• W2083313989 modified "2023-10-17" @default.
• W2083313989 title "Calorimetric investigation of the adsorption of nitrogen bases and nucleosides on a hydrophobic interaction sorbent" @default.
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• W2083313989 doi "https://doi.org/10.1016/j.chroma.2003.10.129" @default.
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