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- W2083318009 abstract "Abstract A new approach to nickel recovery from spent electroless nickel-plating (ENP) solution was investigated using ion-exchange method with brown coal. Nickel ion-exchange was influenced by the solution pH, with the optimum values of pH 9.0–10.0, and was hindered by the anion species existing in the spent solution, especially for the high concentrations of phosphorus compounds. Calcium hydroxide precipitated most of the phosphorus from spent ENP solution, with the highest phosphorus removal efficiency of 98.2%. At the same time, pH control is required to prevent the co-precipitation of nickel hydroxide. Phosphorus removal with CaCO 3 and CaCl 2 showed strong pH dependence. The solution pH dropped with CaCl 2 addition. As a result, the formation of calcium sulphate occurred prior to that of P–Ca compounds. In contrast, CO 3 2− anions from CaCO 3 dissolution reacted with the H + ions to neutralize the solution and decrease CaCO 3 solubility at last, the phosphorus removal reached its maximum of 51%. Combined use of calcium carbonate and calcium chloride improved phosphorus removal, maximizing the phosphorus removal efficiency at 94.8%, and enabling 62% of nickel in the ENP solution to be ion-exchanged into brown coal." @default.
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- W2083318009 date "2015-06-01" @default.
- W2083318009 modified "2023-10-18" @default.
- W2083318009 title "A novel method for nickel recovery and phosphorus removal from spent electroless nickel-plating solution" @default.
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- W2083318009 doi "https://doi.org/10.1016/j.seppur.2015.04.029" @default.
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