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• W2083330645 abstract "Arrhenius rate parameters for the abstraction reactions of methyl radicals, produced by the photolysis of azomethane, with SiH4, SiD4, Si2H6, Si2D6 and φSiD3 were determined in competition with recombination. Silanes are more reactive than their hydrocarbon counterparts, and the increased reactivity is due to lower activation energies, the A factors being similar. The experimental values of Ea have been compared to those calculated by the bond-energy–bond-order method using a simple three-mass-point model. Calculated kinetic isotope effects, based on absolute reaction rate theory, have been compared with experimental results." @default.
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• W2083330645 date "1969-07-15" @default.
• W2083330645 modified "2023-09-26" @default.
• W2083330645 title "Arrhenius Parameters for the Abstraction Reactions of Methyl Radicals with Silanes" @default.
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• W2083330645 doi "https://doi.org/10.1063/1.1672033" @default.
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