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- W2083347829 abstract "In this study, the production of enantiopure benzoin from rac-benzoin acetate was achieved by lipase catalyzed kinetic resolution combined with deracemization using Rhizopus oryzae (CBS111718). The growth cells were pretreated with 20 kHz and 30 kHz ultrasound irradiation and mechanical homogenization. Approximately 100% conversion and 96% enantiomeric excess of the product (S-benzoin) were obtained by applying 20 kHz ultrasound irradiation at pH 6. The deracemization process involves new and important processes that allow for the transformation of a racemate into a single stereoisomeric product in 100% theoretical yields. Moreover, the application of ultrasound increases the conversion rate by reducing mass transfer limitation." @default.
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- W2083347829 date "2010-09-21" @default.
- W2083347829 modified "2023-10-05" @default.
- W2083347829 title "Enantioselective Production of Benzoin from Benzoin Acetate via Kinetic Resolution and Deracemization usingRhizopus oryzae" @default.
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- W2083347829 doi "https://doi.org/10.3109/10731199.2010.516261" @default.
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