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- W2083363670 abstract "A series of luminescent Ln3+@bio-MOF-1 (Ln = Eu, Tb, bio-MOF-1 = Zn8(ad)4(BPDC)6O⋅2Me2NH2 (ad = adeninate, BPDC = biphenyldicarboxylate)) are synthesized via postsynthetic cation exchange by encapsulating lanthanide ions into an anionic metal–organic framework (MOF), and their photophysical properties are studied. After loading 2-thenoyltrifluroacetone (TTA) as sensitized ligand by a gas diffusion (“ship-in-bottle”) method, it is found that the luminescent intensity of Eu3+ is enhanced. Especially, when loading two different lanthanide cations into bio-MOF-1, the luminescent color can be tuned to close white (light pink) light output. Additionally, bio-MOF-1 and Eu3+@bio-MOF-1 are selected as representative samples for sensing metal ions. When bio-MOF-1 is immersed in the aqueous solutions of different metal ions, it shows highly sensitive sensing for Fe3+ as well as Eu3+@bio-MOF-1 immersed in the DMF solutions of different metal ion. The results are benefit for the further application of functionalized bio-MOFs in practical fields." @default.
- W2083363670 created "2016-06-24" @default.
- W2083363670 creator A5072772349 @default.
- W2083363670 creator A5079294349 @default.
- W2083363670 date "2015-08-01" @default.
- W2083363670 modified "2023-10-14" @default.
- W2083363670 title "Photofunctional hybrids of lanthanide functionalized bio-MOF-1 for fluorescence tuning and sensing" @default.
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- W2083363670 doi "https://doi.org/10.1016/j.jcis.2015.03.039" @default.
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