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• W2083367648 abstract "Two new Zn(II) complexes, [Zn(dap)Cl2] (1) and [Zn(dap)2Cl2] (2) (dap stands for 2,3-diaminopyridine), were prepared and spectroscopically and crystallographically characterized. In both compounds, the zinc(II) atom has a pseudo-tetrahedral ZnN2Cl2 coordination environment. Compound 1 adopts a three-dimensional structure built up from [Zn(dap)Cl2]n zig-zag chains, which are linked by N–H⋯Cl hydrogen bonds. In compound 2 the dap is monodentate coordinating via the pyridine nitrogen; the mononuclear tetrahedral [Zn(dap)2Cl2] units are linked into two-dimensional sheets through extensive N–H⋯Cl hydrogen bonding. Inter-sheet π–π interactions connect them into a three-dimensional network." @default.
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• W2083367648 date "2004-03-01" @default.
• W2083367648 modified "2023-10-18" @default.
• W2083367648 title "Extended structures based on hydrogen bonding and π–π interactions: synthesis and characterization of two zinc complexes: [Zn(dap)Cl2] and [Zn(dap)2Cl2]" @default.
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• W2083367648 doi "https://doi.org/10.1016/j.ica.2003.11.035" @default.
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