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• W2083392103 abstract "We report the surface modification of orange-red-emitting hexagonal and monoclinic polymorphs of BiPO4:Eu3+ with oleic acid (OA) for white light generation. The surface-modified hexagonal phase emits white light under near-UV excitation (350–395 nm) through the mixing of broad blue emission from OA and orange-red emission from Eu3+, whereas the same was not observed with the monoclinic phase. The variation in OA emission upon anchoring over the surface of hexagonal BiPO4:Eu3+ resulted in white light generation. Such variation in the interaction of OA with surfaces of BiPO4 polymorphs and surface induced midgap states was established through first-principles calculations that revealed the strong interaction of OA with hexagonal phase. The deduced density of states corroborates the experimental findings on the polymorph-dependent PL properties of OA-modified hexagonal and monoclinic BiPO4:Eu3+." @default.
• W2083392103 created "2016-06-24" @default.
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• W2083392103 date "2014-08-13" @default.
• W2083392103 modified "2023-09-27" @default.
• W2083392103 title "Influence of Structural Polymorphs on Tunable White Light Generation from Orange-Red-Emitting BiPO₄:Eu³⁺ Phosphor by Surface Modification" @default.
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• W2083392103 doi "https://doi.org/10.1021/jp505454n" @default.
• W2083392103 hasPublicationYear "2014" @default.
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