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- W2083397657 abstract "13C NMR is used to study the carbon environment in a dense form of amorphous carbon containing a large fraction of sp3 bonds prepared from a cathodic arc source. The results show a chemical shift of 66 ppm intermediate between graphite and diamond shifts and not previously reported for a pure carbon form. This shift is assigned to the tetrahedral component of the network on the basis of a comparison of various types of NMR techniques and by analogy with the effect of amorphisation on crystalline silicon observed using 29Si NMR. A peak is also observed at 140 ppm which is definitively assigned to sp2 carbon. Cross-polarisation results reveal the presence of approximately 1% of hydrogen which is associated with the tetrahedral network, perhaps in a fashion analogous to the passivation of the dangling bonds in amorphous silicon." @default.
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- W2083397657 date "1995-04-01" @default.
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- W2083397657 title "NMR evidence for strained carbon bonding in tetrahedral amorphous carbon" @default.
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- W2083397657 doi "https://doi.org/10.1016/0301-0104(94)00421-6" @default.
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