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- W2083400854 abstract "A mathematical model was developed to investigate the efficacy of nucleophilic substitution reactions to enhance contaminant mobility during elution processes. The model describes the hydrolysis (SN2 reaction) of N‐2,4,6‐tetranitro‐N‐methylaniline (tetryl), adsorbed onto soil. The reaction products include picrate, methylamine, and nitrite. Picrate the major hydrolysis product (88%) is considerably more soluble than tetryl as well as being biodegradable. Tetryl is recalcitrant to biodegradation. A model was developed to provide a basis for the design of an experimental protocol to investigate the feasibility of this process. The model describes a continuously stirred batch reactor and provides temporal profiles of the contaminant concentrations in both the aqueous and solid phases under a variety of conditions. Although somewhat preliminary in nature, the results indicate that the use of nucleophilic substitution reactions may substantially enhance the efficacy of elution processes for hydrophobic contami..." @default.
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- W2083400854 date "1995-10-01" @default.
- W2083400854 modified "2023-09-24" @default.
- W2083400854 title "Modeing nucleophilic substitution reactions to investigate the feasibility of elution processes" @default.
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- W2083400854 doi "https://doi.org/10.1080/02772249509358206" @default.
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