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- W2083415714 endingPage "1032" @default.
- W2083415714 startingPage "1021" @default.
- W2083415714 abstract "Mossbauer studies combined with magnetic-susceptibility data on well-characterized LaCo${mathrm{O}}_{3}$ in the 4.2-1200-K region show that cobalt ions exist predominantly in the low-spin ${mathrm{Co}}^{mathrm{III}}$ state at low temperatures which transform partially to high-spin ${mathrm{Co}}^{3+}$ ions up to 200 K. Above 200 K, ${mathrm{Co}}^{3+}$ and ${mathrm{Co}}^{mathrm{III}}$ ion pairs transform to ${mathrm{Co}}^{mathrm{II}}$ and ${mathrm{Co}}^{4+}$ pairs. At high temperatures, the population of ${mathrm{Co}}^{3+}$ decreases significantly and completely disappears at the localized-electron-collective-electron transition temperature at 1210 K. The variations of the Lamb-Mossbauer factor and the center shift with temperature provide valuable information on the high-spin-low-spin equilibria, as well as on the nature of the phase transitions and symmetry changes in LaCo${mathrm{O}}_{3}$. All these changes are reflected in the transport properties of LaCo${mathrm{O}}_{3}$. There appears to be little doubt that the first-order localized-electron-collective-electron transition in LaCo${mathrm{O}}_{3}$ is caused essentially by the change in entropy of the $d$ electrons." @default.
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- W2083415714 date "1972-08-01" @default.
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- W2083415714 title "Mössbauer Studies of the High-Spin-Low-Spin Equilibria and the Localized-Collective Electron Transition in LaCo<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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- W2083415714 doi "https://doi.org/10.1103/physrevb.6.1021" @default.
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