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• W2083443325 abstract "The ability of hyperbranched polymers (HBPs) to preferentially segregate to the surface of its matrix owing to its unique structure makes it a good candidate as a surface modifier. One particular challenge in its application as an efficient surface modifier, however, is its possible elimination from the surface due to the lack of attachments between a HBP (modifier) and its host material (polymer matrix). Here, we present a novel approach to efficiently prevent the removal of HBPs from the surface of its host material by directly reacting a HBP containing fluoroalkyl segments (F-HBP) to a multi-functional acrylate monomer prior to curing. We also have characterized surface structure and wettability of the acrylic hard coating material by X-ray photoelectron spectroscopic and contact angle measurements, respectively. The results show that since F-HBP was segregated at the surface, the surface became hydrophobic and more stable. Thus, we claim that our approach results in the formation of a water-repellent acrylic hard coating material." @default.
• W2083443325 created "2016-06-24" @default.
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• W2083443325 date "2013-02-01" @default.
• W2083443325 modified "2023-10-02" @default.
• W2083443325 title "Hydrophobic acrylic hard coating by surface segregation of hyper-branched polymers" @default.
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• W2083443325 doi "https://doi.org/10.1016/j.apsusc.2012.11.160" @default.
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