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• W2083542984 abstract "Chiral and racemic Salen-type Schiff-base ligands (H2L1, H2L2 and H2L3), condensed between D-(+)- and D,L-camphoric diamine (also known as (1R,3S)-1,2,2-trimethylcyclopentane-1,3-diamine) and 2-hydroxybenzaldehyde or 3,5-dibromo-2-hydroxybenzaldehyde with a 1:2 molar ratio, have been synthesized and characterized. A series of new nickel(II), palladium(II) and copper(II) complexes of these chiral and racemic ligands exhibiting different coordination number (4, 5 and 6) have been characterized with the formulae [NiL1]·CH3OH (3), [NiL1]·H2O (4), [NiL2] (5), [PdL2] (6), [Cu2(L2)2(H2O)] (7) and [NiL3(DMF)(H2O)] (8). Different solvent molecules in 3 and 4 (methanol and water molecules) as well as different apical ligands in 7 and 8 (water and DMF molecules) are involved in different O–H···O hydrogen bonding interactions to further stabilize the structures. UV–Vis (UV–Vis), circular dichroism (CD) spectra and thermogravimetric (TG) analyses for the metal complexes have also been carried out." @default.
• W2083542984 created "2016-06-24" @default.
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• W2083542984 date "2010-02-01" @default.
• W2083542984 modified "2023-10-10" @default.
• W2083542984 title "Salen-type nickel(II), palladium(II) and copper(II) complexes having chiral and racemic camphoric diamine components" @default.
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• W2083542984 doi "https://doi.org/10.1016/j.poly.2009.12.021" @default.
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