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• W2083574657 abstract "Optical probe-beam deflection signals, together with cyclic voltammograms, have been used to analyse the electron-transfer process at electrodes coated with [Ru(bpy)2ClPVP]Cl, polyaniline and poly(1-hydroxyphenazine). With this technique it is possible to determine if anions or cations are used as the charge-compensating ions in the electron-transfer process. The electron transfer at [Ru(bpy)2ClPVP]Cl was shown to be accompanied by a simple counter-ion diffusion process. The known electron-transfer mechanism of polyaniline was confirmed and a plausible mechanism for the electron transfer of poly(l-hydroxyphenazine) has been proposed. The additional information (direction of concentration gradients) obtained by a simple probe-beam deflection experiment is extremely useful in the analysis of reaction mechanisms at redox polymer-coated electrodes." @default.
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• W2083574657 date "1991-01-01" @default.
• W2083574657 modified "2023-09-27" @default.
• W2083574657 title "Mechanistic investigations of redox polymer-coated electrodes using probe-beam deflection and cyclic voltammetry" @default.
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• W2083574657 doi "https://doi.org/10.1039/ft9918700939" @default.
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