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- W2083583715 abstract "Reaction of [Me 2 Al{RNS(Me)NR}] 2 (R = 2,6-Me 2 C 6 H 3 ) with t-BuOH affords N -methylthio- N -(2,6-dimethylphenyl)-2,6-dimethyl-1,4-quinonediimine in 67% yield. The X-ray structure of this compound shows that two conformational isomers are present in the solid. Temperature dependent 13 C and 1 H NMR measurements show that in solution these conformers exchange at a rate which is fast on the NMR time scale at + 60°C and slow at − 60 °C. From the coalescence point of two of the 13 C resonances, the free energy of activation is estimated to be 13.7 + 1.0 kcal mol at 10°C. Possible processes for the exchange are discussed, and also a reaction scheme for the formation of the title compound is discussed." @default.
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- W2083583715 date "1981-10-01" @default.
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- W2083583715 title "X-ray structure and dynamic behaviour in solution of N-methylthio-N'-2,6-dimethylphenyl).2,6-dimethyl-1,4-quinonediimine formed by the alcoholysis of [Me2 Al{2,6-Me2C6H3NS(Me)NC6H3Me2-2,6}]2" @default.
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- W2083583715 doi "https://doi.org/10.1016/0022-328x(81)85004-8" @default.
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