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- W2083586175 abstract "Abstract The water exchange reaction of [Pd(dien)H2O]2+ (dien = diethylenetriamine) was studied as function of temperature (268-308 K) and pressure 0.1-197 MPa) using 17O NMR techniques. The rate and activation parameters are: kcx = 5100 s−1 at 298 K; ΔH# =38 kJ mol−1; ΔS# = -47 JK−1 mol−1; ΔV# = -2.8 cm3 mol−1 at 296 K. The results are discussed in reference to solvent exchange data for other Pt(II) and Pd(II) complexes, and are interpreted in terms of an associatively activated substitution process." @default.
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- W2083586175 date "1989-12-01" @default.
- W2083586175 modified "2023-09-26" @default.
- W2083586175 title "High pressure <sup>17</sup>O NMR study of solvent exchange on square planar complexes: Water exchange on [Pd(dien)H<sub>2</sub>O]<sup>2+</sup>" @default.
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- W2083586175 doi "https://doi.org/10.1080/08957958908201031" @default.
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