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- W2083602656 abstract "The influence of crystal mixing on the structural phase transitions in ${mathrm{Rb}}_{1mathrm{ensuremath{-}}mathrm{x}}$${mathrm{Cs}}_{mathrm{x}}$${mathrm{CaF}}_{3}$ (01) fluoroperovskite crystals has been studied by thermal expansion and EPR measurements of ${mathrm{Ni}}^{2+}$ and ${mathrm{Ni}}^{3+}$ paramagnetic probes. A cubic-to-tetragonal phase transition has been detected in crystals with x=0, 0.1, 0.21, 0.27, and 0.35. The critical temperature and the tetragonal distortion decrease as x increases. No transition was observed for xensuremath{geqslant}0.44. This transition shows a weak first-order component in the x=0 and 0.1 samples, which is progressively smeared out for x>0.1, indicating a spatial distribution of the critical temperature in those crystals with high ionic substitution rate. In ${mathrm{RbCaF}}_{3}$ , another structural phase transition was observed at 20 K with a thermal hysteresis between 20 and 40 K. This transition has not been found in any of the mixed crystals." @default.
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- W2083602656 date "1997-04-01" @default.
- W2083602656 modified "2023-10-14" @default.
- W2083602656 title "Cubic-to-tetragonal structural phase transition inRb1−xCsxCaF3solid solutions: Thermal expansion and EPR studies" @default.
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- W2083602656 doi "https://doi.org/10.1103/physrevb.55.8148" @default.
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