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- W2083639211 abstract "Secondary carbanions [CHXY]–(X,Y = CN, CO2Et) react with the η1-chlorocarbyne ligand in [L(CO)2MCCl][L = hydrotris(3,5-dimethylpyrazol-1-yl)borate, M = Mo, W] to yield the first isolable anionic group 6 η1-vinylidene complexes [L(CO)2M(C·CXY)]– and reaction of the latter (M = Mo, X = CN or CO2Et, Y = CO2Et) with a variety of electrophilic or oxidising reagents yields in each case a single neutral product, one example of which has been crystallographically characterised as the 7-co-ordinate oxametallacyclic carbene complex [L(CO)2[graphic omitted]]; in contrast HgX2, CuI, and [ArN2]BF4 yield novel highly functionalised carbyne complexes [L(CO)2MC·C(CN)(CO2Et)(Z)] where Z = HgX, Cu, and N2Ar respectively." @default.
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- W2083639211 date "1988-01-01" @default.
- W2083639211 modified "2023-10-14" @default.
- W2083639211 title "Stable anionic η<sup>1</sup>-vinylidene complexes of molybdenum and tungsten" @default.
- W2083639211 doi "https://doi.org/10.1039/c39880001606" @default.
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