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- W2083656420 abstract "The noncatalytic, gas-phase combustion reaction between ammonia and air was studied in an adiabatic, well-stirred reactor. Results indicated an Arrhenius expression for the over-all reaction of the form −(d/dt)[NH3]=10B exp(−E/RT)[NH3]f[O2]n−f (mole/cm3-sec) with best fit values B=13.63±0.22 standard deviation E=34.77 (kcal/mole)±1.65 f=0.75±0.12 n=1.95±0.11Inlet temperatures were varied from 350° to 470°K, gas temperatures from 1550° to 1900°K, ammonia concentrations from 0.5×10−4 to 3.25×10−4 mole/liter, oxygen concentrations from 1.5×10−4 to 4.0×10−4 mole/liter, and pressure from 1/2 to 1 atm.A blowout or stability map was also obtained, and an empirical correction for variation of inlet temperature was established, of the form I4=I exp[(400−Ti)/ψ()].Experience with both the slow and fast oxidation reactions indicate that interaction with the reactor wall plays an important role in the kinetic mechanism for the slow reaction, but not for the fast reaction." @default.
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- W2083656420 date "1965-09-01" @default.
- W2083656420 modified "2023-10-14" @default.
- W2083656420 title "Homogeneous combustor stability" @default.
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- W2083656420 doi "https://doi.org/10.1016/0010-2180(65)90100-8" @default.
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