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• W2083658719 abstract "The study investigates the stability of gadolinium-DTPA complex in presence of competing metallic ions, Fe(3+), Cu(2+) and Zn(2+) using batch experiments and coagulation-flocculation simulations. High performance liquid chromatography with fluorescence detection was used for simultaneous analysis of chelate gadolinium (Gd-DTPA) and free Gd(III) ion in water. It was shown that Cu(2+) has a strong affinity for DTPA and could lead to a complete release of Gd(3+). Fe(3+) appeared also to compete strongly with Gd(3+) for DTPA binding since up to 80% of Gd-complex was dissociated under iron excess condition. Finally, zinc had a lower influence on Gd speciation: only 15% of Gd(3+) was released with addition of a 5-fold excess of Zn(2+). During coagulation-flocculation simulation, Fe(3+) was able to displace about 27% of Gd-DTPA, and no adsorption was observed onto flocs." @default.
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• W2083658719 date "2014-01-01" @default.
• W2083658719 modified "2023-09-26" @default.
• W2083658719 title "Transmetallation of Gd-DTPA by Fe3+, Cu2+ and Zn2+ in water: Batch experiments and coagulation–flocculation simulations" @default.
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• W2083658719 doi "https://doi.org/10.1016/j.chemosphere.2013.09.102" @default.
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