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- W2083661978 abstract "In the present paper an investigation of the influence of impurity ions on the evaporation of NaCl crystals is reported. Monovalent impurities little influence the evaporation rate. The evaporating structures have changed only when there were extremal differences in the values of ionic radii. However, the bivalent impurities substantially influence the evaporation rate. This unfluence depends upon the fact whether the impurities are in non-associated or associated state with cation vacancies, respectively. This fact also affects the shape of evaporating structure. Es wird der Einfluß von Fremdionen auf die Verdampfung von NaCl-Kristallen untersucht. Einwertige Ionen zeigen wenig Wirkung auf die Verdampfungsgeschwindigkeit. Die Verdampfungsstrukturen waren nur verändert, wenn sich die Ionenradien stark voneinander unterschieden. Zweiwertige Fremdionen beeinflussen die Verdampfungsgeschwindigkeit dagegen stark. Dieser Einfluß hängt davon ab, ob sich die Fremdionen in nichtassoziiertem oder assoziiertem Zustand mit den Kationen-Leerstellen befinden. Diese Situation beeinflußt auch die Form der Verdampfungsstruktur." @default.
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- W2083661978 date "1976-01-01" @default.
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- W2083661978 title "Evaporation of doped NaCl crystals" @default.
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- W2083661978 doi "https://doi.org/10.1002/crat.19760110706" @default.
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