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- W2083663486 abstract "Raman measurements have been performed on the mixed system (NH4)C11−xBrx, in the tetragonal phase. For intermediate x-values, new peaks are found in the acoustical frequency region of the spectra, whose mode strengths are proportional to x and (1 - x), respectively. Adopting the assumption that the concept of a Brillouin zone is still useful in a mixed crystal, the Raman active modes of the tetragonal phase of the mixed crystals are identified with the M-point modes of the cubic β-phase. The experimental data are compared with a simple calculation based on the REI-model. Am Mischsystem (NH4)Cl1−xBrx in der tetragonalen Phase wurden Ramanmessungen durchgeführt. Im akustischen Frequenzbereich der Spektren werden für mittlere x-Werte neue Moden gefunden, deren Intensitäten proportional zu x beziehungsweise (1 - x) sind. Unter der Annabme, daß das Konzept der Brillouin-Zone auch fur einen Mischkristall an-wendbar ist, können die ramanaktiven Moden der tetragonalen Phase der Mischkristalle mit den M-Punkt-Moden der kubischen β-Phase identifiziert werden. Die experimentellen Ergebnisse werden mit einer einfachen, auf dem REI-Modell basierenden Rechnung verglichen." @default.
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- W2083663486 date "1974-05-01" @default.
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- W2083663486 title "Raman Scattering Studies on (NH4)Cl1−xBrx Mixed Crystals in the Tetragonal Phase" @default.
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- W2083663486 doi "https://doi.org/10.1002/pssb.2220630139" @default.
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