Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083669683> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2083669683 endingPage "110" @default.
- W2083669683 startingPage "105" @default.
- W2083669683 abstract "Treatment of TiCl2(TADDOLate)(THF)2 (1) (TADDOL=α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanol) with 1 molar equiv. of bidentate dibenzoylmethanate (Li+dbm−) afforded the monomeric Ti(TADDOLate)(dbm)Cl(THF) (2). While recrystallization of 1 but without careful exclusion of moisture, an unexpected binuclear Ti(IV) complex 3 containing a bridging (2R,3R)-1,1,4,4-tetraphenyl-1,3-dihydoxy-2,4-dioxobutane (4) was isolated as colorless crystals. The bridging chiral ligand 4 was derived from the TADDOL ligand with loss of the ketal group. When 1 was reacted with lithium acetylacetonate (Li+acac−), another unexpected binuclear Ti(IV) complex 5 containing the same bridging chiral ligand 4 and an acac− ligand was obtained. Complexes 1, 2, 3 and 5 were subjected to X-ray structural analyses and solid state structures show that complexes 1 and 2 are monomeric species with the only difference from the replacement of one Cl− and one THF ligand in 1 by a bidentate dbm− ligand in 2. Complexes 3 and 5 are binuclear species with the replacement of also one Cl− and one THF ligand on one metal center in 3 by the acac− ligand in 5." @default.
- W2083669683 created "2016-06-24" @default.
- W2083669683 creator A5008929233 @default.
- W2083669683 creator A5010125905 @default.
- W2083669683 creator A5036868926 @default.
- W2083669683 date "2001-03-01" @default.
- W2083669683 modified "2023-09-26" @default.
- W2083669683 title "Synthesis and structure of Ti(TADDOLate)(dbm)Cl(THF) and structures of two binuclear Ti(IV) complexes containing a bridging ligand derived from the TADDOL ligand" @default.
- W2083669683 cites W1543557196 @default.
- W2083669683 cites W1965347902 @default.
- W2083669683 cites W1985804456 @default.
- W2083669683 cites W1999408378 @default.
- W2083669683 cites W2007391722 @default.
- W2083669683 cites W2008657983 @default.
- W2083669683 cites W2012993407 @default.
- W2083669683 cites W2016435622 @default.
- W2083669683 cites W2026838218 @default.
- W2083669683 cites W2027029146 @default.
- W2083669683 cites W2036219982 @default.
- W2083669683 cites W2044864014 @default.
- W2083669683 cites W2073152413 @default.
- W2083669683 cites W2461064233 @default.
- W2083669683 cites W2593806967 @default.
- W2083669683 cites W2799007049 @default.
- W2083669683 cites W2950122163 @default.
- W2083669683 cites W2951030126 @default.
- W2083669683 cites W1968124833 @default.
- W2083669683 doi "https://doi.org/10.1016/s0020-1693(01)00291-2" @default.
- W2083669683 hasPublicationYear "2001" @default.
- W2083669683 type Work @default.
- W2083669683 sameAs 2083669683 @default.
- W2083669683 citedByCount "12" @default.
- W2083669683 countsByYear W20836696832012 @default.
- W2083669683 countsByYear W20836696832016 @default.
- W2083669683 crossrefType "journal-article" @default.
- W2083669683 hasAuthorship W2083669683A5008929233 @default.
- W2083669683 hasAuthorship W2083669683A5010125905 @default.
- W2083669683 hasAuthorship W2083669683A5036868926 @default.
- W2083669683 hasConcept C115624301 @default.
- W2083669683 hasConcept C116569031 @default.
- W2083669683 hasConcept C155647269 @default.
- W2083669683 hasConcept C166940927 @default.
- W2083669683 hasConcept C170493617 @default.
- W2083669683 hasConcept C178516000 @default.
- W2083669683 hasConcept C178790620 @default.
- W2083669683 hasConcept C185592680 @default.
- W2083669683 hasConcept C188027245 @default.
- W2083669683 hasConcept C2777588596 @default.
- W2083669683 hasConcept C521977710 @default.
- W2083669683 hasConcept C55352516 @default.
- W2083669683 hasConcept C55493867 @default.
- W2083669683 hasConcept C71240020 @default.
- W2083669683 hasConcept C8010536 @default.
- W2083669683 hasConceptScore W2083669683C115624301 @default.
- W2083669683 hasConceptScore W2083669683C116569031 @default.
- W2083669683 hasConceptScore W2083669683C155647269 @default.
- W2083669683 hasConceptScore W2083669683C166940927 @default.
- W2083669683 hasConceptScore W2083669683C170493617 @default.
- W2083669683 hasConceptScore W2083669683C178516000 @default.
- W2083669683 hasConceptScore W2083669683C178790620 @default.
- W2083669683 hasConceptScore W2083669683C185592680 @default.
- W2083669683 hasConceptScore W2083669683C188027245 @default.
- W2083669683 hasConceptScore W2083669683C2777588596 @default.
- W2083669683 hasConceptScore W2083669683C521977710 @default.
- W2083669683 hasConceptScore W2083669683C55352516 @default.
- W2083669683 hasConceptScore W2083669683C55493867 @default.
- W2083669683 hasConceptScore W2083669683C71240020 @default.
- W2083669683 hasConceptScore W2083669683C8010536 @default.
- W2083669683 hasIssue "1-2" @default.
- W2083669683 hasLocation W20836696831 @default.
- W2083669683 hasOpenAccess W2083669683 @default.
- W2083669683 hasPrimaryLocation W20836696831 @default.
- W2083669683 hasRelatedWork W1977508118 @default.
- W2083669683 hasRelatedWork W2035452887 @default.
- W2083669683 hasRelatedWork W2061685652 @default.
- W2083669683 hasRelatedWork W2071095568 @default.
- W2083669683 hasRelatedWork W2083669683 @default.
- W2083669683 hasRelatedWork W2094541312 @default.
- W2083669683 hasRelatedWork W2167124483 @default.
- W2083669683 hasRelatedWork W2198139765 @default.
- W2083669683 hasRelatedWork W2739936718 @default.
- W2083669683 hasRelatedWork W2743877392 @default.
- W2083669683 hasVolume "314" @default.
- W2083669683 isParatext "false" @default.
- W2083669683 isRetracted "false" @default.
- W2083669683 magId "2083669683" @default.
- W2083669683 workType "article" @default.