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- W2083672816 abstract "A new reaction cascade to give tricyclic cores of 2,4-dihydro-1H-azeto[1,2-a]quinolines (benzocarbacephems) and pyrrolo[1,2-a]quinolines starting from acyclic N-aryl ketonitrones and acceptor ring substituted methylenecyclopropanes has been reported. This reaction includes 1,3-dipolar cycloaddition of N-aryl-C,C-diaryl or N-aryl-C,C-bis(methoxycarbonyl) nitrones 1 to the double bond of dimethyl methylenecyclopropane-1,2-dicarboxylate 2 or benzylidenecyclopropane-1,1-dicarboxylate 3, followed by Brandi–Guarna rearrangement of the initially formed 5-spirocyclopropane-isoxazolidine cycloadducts to give 2,4-dihydro-1H-azeto[1,2-a]quinolines 4 or pyrrolo[1,2-a]quinolines 6." @default.
- W2083672816 created "2016-06-24" @default.
- W2083672816 creator A5001011772 @default.
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- W2083672816 creator A5054606157 @default.
- W2083672816 creator A5065397487 @default.
- W2083672816 creator A5089752696 @default.
- W2083672816 date "2012-02-24" @default.
- W2083672816 modified "2023-09-27" @default.
- W2083672816 title "Cycloaddition of C,C-Disubstituted Ketonitrones with Acceptor Methylenecyclopropanes and Subsequent Rearrangement Cascade of 5-Spirocyclopropane-isoxazolidines" @default.
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- W2083672816 doi "https://doi.org/10.1002/ejoc.201200039" @default.
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