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- W2083747339 abstract "Abstract A kinetic study of the reaction of [Pt(ol)Cl 3 ] - (ol=allylNH 3 = , allylPEt 3 = , allylSO 3 , pent-4-enylNH 3 = with bipyridyl (Bipy) in acidic 95 percent aqueous methanol to give cis-[Pt(Bipy)Cl 2 ] is reported. The rate law takes the form 1/k obs =k(Cl - )/(Bipy), where k obs is the pseudo-first-order rate constant. The proposed mechanism involves slow formation of the solvato species [Pt(ol)(S)Cl 2 ] followed by slow reaction with Bipy to give the final product with replacement of the coordinated olefin." @default.
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- W2083747339 date "1970-01-01" @default.
- W2083747339 modified "2023-09-25" @default.
- W2083747339 title "Olefin replacement by bipyridyl in Platinum(II) olefin complexes" @default.
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- W2083747339 doi "https://doi.org/10.1016/s0020-1693(00)93368-1" @default.
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