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- W2083771330 endingPage "588" @default.
- W2083771330 startingPage "584" @default.
- W2083771330 abstract "The stereoselective construction of complex molecules with multiple stereogenicity in a single step represents an extremely useful, but challenging approach to complexity in chemical synthesis. The development of organocatalytic cascade processes has proven useful in these studies, but reports where four or more stereocentres are created in a single step from just two achiral reagents are rare. Herein we report the development of a novel asymmetric domino Michael-Michael reaction between nitrohex-4-enoates and nitro-olefins to generate cyclohexanes of high complexity, including one with a quaternary centre, and three with five contiguous stereocentres. This methodology provides access to a range of useful nitrocyclohexane derivatives, including a novel class of α-lycorane-like structures." @default.
- W2083771330 created "2016-06-24" @default.
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- W2083771330 date "2012-01-01" @default.
- W2083771330 modified "2023-09-26" @default.
- W2083771330 title "Organocatalytic enantioselective construction of nitrocyclohexanes containing multiple chiral centres via a cascade reaction" @default.
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- W2083771330 doi "https://doi.org/10.1039/c1sc00592h" @default.
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